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原位聚合法在石墨烯/聚合物纳米复合材料中的应用 被引量:11

Use of in-situ polymerization in the preparation of graphene/polymer nanocomposites
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摘要 石墨烯作为一种新型炭材料,2004年通过简单的机械剥离方法制备得到。而氧化石墨烯作为石墨烯的氧化状态,其基面和边缘上存在大量的含氧官能团,可以很好地分散在水中,因而具有很好的加工性和广阔的应用前景,引起了学界的广泛重视。原位聚合法作为一种常用聚合方法,被广泛应用于合成石墨烯/聚合物纳米复合材料。本文着重介绍了石墨烯及氧化石墨烯的定义、不同的制备方法、原位聚合法的基本原理,及其在石墨烯/聚合物纳米复合材料制备过程中的应用进展。 Graphene oxide(GO) has a large number of oxygen-containing functional groups on the basal planes and edges, which makes easily dispersed in water and broadens its prospective use. In-situ polymerization, a common polymerization technique, is widely used in the synthesis of graphene/polymer nanocomposites. This paper considers the different preparation methods of graphene and graphene oxide, and the basic principle of in-situ polymerization and its use in the preparation of graphene or GO/polymer nanocomposites, including GO/polyimide, GO/epoxy, GO/polyurethane, GO/polystyrene, graphene/polyaniline, GO/polyaniline, GO/polyvinyl alcohol and GO/polydopamine。
作者 毛赫南 王晓工 MAO He-nan;WANG Xiao-gong(Department of Chemical Engineering,Laboratory of Advanced Materials(MOE),Tsinghua University,Beijing 100084)
出处 《新型炭材料》 SCIE EI CAS CSCD 北大核心 2020年第4期336-343,共8页 New Carbon Materials
关键词 石墨烯 氧化石墨烯 原位聚合 纳米复合材料 Graphene Graphene oxide In-situ polymerization Nanocomposites
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