摘要
Li[NixMnyCoz]O2 cathodes are currently the most practicable materials in the timing of developing high-performance rechargeable batteries for next-generation technologies.With the ever-growing demand for energy density,a significant breakthrough has been achieved by the controllable concentration design forming core-shell and concentration gradient structures to push Li[NixCoyMnz]O2 toward higher energy density,longer lifetime and safety.Herein,we review the recent progress on advanced concentration gradient cathode materials.Furthermore,we prospect that this novel approach will continuously extend its advantages in developing extremely fast charging and Co-free cathode materials in the near future.
基金
T.Liu and K.Amine gratefully acknowledge support from the U.S.Department of Energy(DOE)
Office of Energy Efficiency and Renewable Energy
Vehicle Technologies Office
Argonne National Laboratory is operated for DOE Office of Science by UChicago Argonne,LLC,under contract number DE-AC02-06CH11357。