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α-大马酮的制备工艺研究

Preparation process of alpha-damascone
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摘要 α-大马酮作为香料在食品、化妆品等领域有着广泛的应用,因生产工艺的限制国内的生产厂家较少。本文提出一种新的制备α-大马酮的制备工艺,选用价格较为低廉的α-紫罗兰酮为原料,经羰基的肟化、双键的环氧化、脱水和还原反应得到α-大马酮。该路径操作简便,收率高,成本低,是一种适合工业化生产α-大马酮的方法。 The alpha-damascenone is widely used in food and cosmetics as a spice.There are few manufacturers of the alpha-damascenone in China due to technical limitations.A new synthesizing route was proposed by using the low-cost raw material of alpha-ionone,and the alpha-damascenone can be synthesized through oximation of carbonyl,epoxidation of double bond,dehydration,and reduction.This route is easy and simple with high yield and low cost,and is applicable to industrial production.
作者 胡君一 王龙龙 徐英黔 潘常升 郭爱强 未兴福 胡知之 吴希慧 HU Junyi;WANG Longlong;XU Yingqian;PAN Changsheng;GUO Aiqiang;WEI Xingfu;HU Zhizhi;WU Xihui(School of Chemical Engineering,University of Science and Technology Liaoning,Anshan 114051,China;Jijia Geen Building Tchnology Co.,LTD,Anshan114051,China)
出处 《辽宁科技大学学报》 CAS 2019年第3期197-201,共5页 Journal of University of Science and Technology Liaoning
关键词 α-大马酮 α-紫罗兰酮 制备 alpha-damascenone alpha-ionone preparation
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