摘要
超高交联聚合物主要是通过傅克烷基化反应来制备的,具有合成简单、多孔、无毒、结构稳定、质轻等特点。本文介绍了傅克烷基化反应的条件和机理,展示了超高交联聚合物的合成方法及这些材料在气体储存/分离、水处理、催化、传感等领域中的应用,并对傅克烷基化反应与超高交联聚合物的进一步结合做出了展望。
Constructed mainly via Friedel-Crafts alkylation reaction,hypercrosslinked polymers(HCPs) possess significant advantages,such as easy to synthesize,porous,non-toxic,structurally stable and lightly weighted.This paper briefly describes the general reaction conditions and mechanism of the conversion.Meanwhile,the synthesis strategy of some HCP materials and their diverse applications in gas adsorption/separation,water-treatment,catalysis,and sensing etc.are also be displayed here.Additionally,we point out the further combination between Friedel-Crafts alkylation reaction and HCPs in the future.
出处
《大学化学》
CAS
2017年第12期1-11,共11页
University Chemistry
基金
河南省高等学校重点科研项目(18A150006)
国家自然科学基金(21702049)
关键词
傅克烷基化反应
超高交联聚合物
吸附
催化
Friedel-Crafts reaction
Hypercrosslinked polymers
Absorption
Catalysis
