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Effect of Temperature and Phase Constitution on Kinetics of La Diffusion 被引量:7

Effect of Temperature and Phase Constitution on Kinetics of La Diffusion
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摘要 The diffusion of La in ε-Fe 2~3N(ε)and γ′-Fe 4N (γ′)phases produced by plasma nitriding was studied. It is found that with increasing nitriding time, the ε phase continuously decomposes into γ′ one under employed experimental conditions and compared with γ′ phase or ε+γ′ ones, the mono one ε has an impedient effect on depth of La diffusion. The growth of La layer in dual phases and mono one follows an approximate exponential law and a parabolic one, respectively, and this kinetics law does not change with increasing temperature. The effect of increasing temperature in the range of 520 to 560 ℃ on La diffusion depth is less than that of phase constitution change such as the decomposition of ε phase into γ′ one. The diffusion of La in ε-Fe 2~3N(ε)and γ′-Fe 4N (γ′)phases produced by plasma nitriding was studied. It is found that with increasing nitriding time, the ε phase continuously decomposes into γ′ one under employed experimental conditions and compared with γ′ phase or ε+γ′ ones, the mono one ε has an impedient effect on depth of La diffusion. The growth of La layer in dual phases and mono one follows an approximate exponential law and a parabolic one, respectively, and this kinetics law does not change with increasing temperature. The effect of increasing temperature in the range of 520 to 560 ℃ on La diffusion depth is less than that of phase constitution change such as the decomposition of ε phase into γ′ one.
出处 《Journal of Rare Earths》 SCIE EI CAS CSCD 2002年第4期329-332,共4页 稀土学报(英文版)
基金 ProjectsupportedbytheEuropeanCommissionunderBRITE/EURAMProgrammeBPRP CT970 5 46andbytheNationalNaturalScienceFoundationofChina ( 5 0 0 710 2 0 )
关键词 rare earths TEMPERATURE phase constitution La diffusion KINETICS rare earths temperature phase constitution La diffusion kinetics
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