摘要
以酸/碱改性和Cu负载活性炭为催化剂,采用微气泡催化臭氧氧化深度处理化工园区废水。结果表明,经该工艺处理后,出水COD降至20 mg/L以下,发光抑制率降至-1.2%^-7.3%,B/C升至0.29~0.37,消除了废水生物毒性,并提高了废水可生化性。硝酸改性并负载Cu组分活性炭具有更强的催化活性,COD去除率和去除负荷分别可达70.8%和0.478 kg/(m^3·d),臭氧利用率为97.5%,催化臭氧氧化反应效率为0.554 mg COD/mgO_3。
The micro-bubble catalytic ozonation process has been applied to the advanced treatment of wastewater from chemical industrial parks,using acid/alkali modified and Cu-loaded activated carbon as catalyst. The results show that after treated by this process,the effluent COD is reduced to less than 20 mg/L,luminescence inhibition rate decreased to-1.2%-7.3%,B/C increased to 0.29-0.37,the wastewater bio-toxicity eliminated and wastewa-ter biodegradability improved. Since the nitric acid modified and Cu-loaded activated carbon has stronger activity , the COD removing rate and removal loading can reach 70.8%and 0.478 kg/（m3·d）,respectively,the ozone utiliza-tion rate is 97.5%and catalytic ozonation efficiency 0.554 mgCOD/mgO3.
作者
茹星瑶
押玉荣
张静
王晓磊
陈晓轩
吴江渤
刘春
Ru Xingyao Ya Yurong Zhang Jing Wang Xiaolei Chen Xiaoxuan Wu Jiangbo Liu Chun(Jiacheng Environmental Protection Engineering Co., Ltd., Hebei Wastewater Treatment and Resource Engineening Technology Research Center, Shijiazhuang 050031, China Pollution Prevention Biotechnology Laboratory of Hebei Province ,School of Environmental Science and Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, China)
出处
《工业水处理》
CSCD
北大核心
2017年第10期57-60,共4页
Industrial Water Treatment
基金
河北省自然科学基金项目(E2015208140)
2015年石家庄市裕华区科学技术研究与发展计划课题
关键词
微气泡
催化臭氧氧化
化工园区废水
深度处理
micro-bubble
catalytic ozonation
wastewater from chemical industrial parks
advanced treatment
