摘要
以2,4-二羟基二苯甲酮、氯乙酰氯、2,2,6,6-四甲基哌啶胺等为主要原料,经两步亲核取代反应,合成了一种双功能受阻胺光稳定剂。目标产物结构经1H NMR、13C NMR、FT-IR和ESI-HRMS分析进行了确认,并对其进行抗老化性能测试,结果表明其具备良好的防止聚合物光老化的性能。
A bifunctional hindered amine light stabilizer （HALS） was designed and synthesized from 2,4-dihydroxybenzophenone,chloroacetyl chloride and 2,2,6,6-tetramethylpiperidine-4-amine through twostep nucleophilic substitutions.The structure of the target compound was confirmed by 1H NMR,13C NMR,FT-IR and ESI-HRMS.Its anti-oxidant and anti-aging properties were evaluated.The obtained results indicate that this synthesized stabilizer is efficient for inhibiting degradation of polymer materials with good oxidation resistance and photo-stabilization.
作者
桂思喆
原燕燕
罗浩
刘娜
陈立功
Gui Sizhe Yuan Yanyan Luo Hao Liu Na Chen Ligong(School of Chemical Engineering and Technology, Tianjin University, Tianjin 300354, China Tianjin Engineering Research Center for Functional Fine Chemicals, Tianjin 300354, China Collaborative Innovation Center of Chemical Science and Engineering, Tianjin, 300072, China)
出处
《化学工业与工程》
CAS
CSCD
2017年第5期61-64,共4页
Chemical Industry and Engineering
关键词
受阻胺光稳定剂
紫外线吸收剂
抗老化性能
hindered amine light stabilizer
ultraviolet light absorber
anti aging property
