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超临界流体色谱-气相色谱质谱法测定主流烟气中酯类化合物 被引量:5

Determination of esters in mainstream cigarette smoke by supercritical fluid chromatography and gas chromatography-mass spectrometry
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摘要 构建了一种超临界色谱(SFC)-GC-MS方法,并用来检测卷烟主流烟气粒相物中酯类物质。用超临界流体对捕集卷烟主流烟气粒相物的剑桥滤片进行萃取,将萃取得到的香气成分用SFC进行初步分离,划分成3段,将分离出的3段馏分,分别用GC/M S进行检测分析。检测数据显示,样品不分段直接进样用GC/MS分析,总共检测出了11种酯类化合物;然而,经SFC分段后,再用GC/MS分析,总共检测出了31种酯类化合物。经SFC分离后的各段化合物峰形较好,基本不重叠,为主流烟气中酯类成分检测提供一种新方法。 General gas chromatography-mass spectrometry (GC/MS) method often suffers from the limited capacity of chromatographic column, and can not accurate analyze ingredients in mainstream smoke. To resolve this problem, a supercritical fluid chromatography (SFC)-GC/MS method was developed for the determination of esters in mainstream cigarette smoke. Total particulate matter of mainstream cigarette smoke was collected by a Cambridge filter pad and then the Cambridge filter pad was extracted by supercritical fluid extractor. Next, the extract was separated and divided into 3 fractions by SFC, and each fraction was analyzed by GC/MS. The test data suggested that 11 kinds of esters were detected without SFC separation, and 31 kinds of esters were assayed using the SFC-GC/ MS technique. The chromatographic column capacity of GC/MS was improved and overlapping chromatographic peaks are avoided by this SFC-GC/MS approach. Consequently, this SFC-GC/MS method is a novel platform for esters assay.
出处 《分析试验室》 CAS CSCD 北大核心 2017年第4期384-388,共5页 Chinese Journal of Analysis Laboratory
基金 国家自然科学基金(21365026) 云南省科学技术厅科技项目(2014FD078) 云南中烟工业有限责任公司技术中心项目(JSZX2014JC04)资助
关键词 卷烟主流烟气 气相色谱-质谱法 超临界流体色谱 酯类化合物 Mainstream cigarette smoke Gas chromatography-mass spectrometry Supercritical fluid chromatography Esters
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