摘要
为了提高有机太阳能电池的全光谱吸收,本文设计了一种含长碳链的硫代双烯镍配合物作为电池的活性材料。以1-萘酚和溴代正辛烷为原料制备烷氧基萘中间体,再与草酰氯进行付克反应得到对称的中间体二酮,最后与氯化镍络合反应制备了含长碳链萘基硫代双烯镍配合物目标物。该配合物结构通过IR、1H-NMR和13CNMR进行了表征,其光热稳定性通过UV和TG测试。
In order to improve the full spectrum absorption of organic solar cells,a dithiolene nickel complexes with long carbon chain was designed and prepared as an active material of the cell. Alkoxynaphthalene was synthesized from 1-naphthol and bromooctane,and then symmetric diketone was prepared by Friedel-Crafts reaction of oxalyl chloride and alkoxynaphthalene in methylene chloride solvents,finally the target product of dithiolene nickel complexe was obtaineded by complex reaction. The structure of target compound was characterized by IR、1H-NMR and13C-NMR. The photo and thermal stability were investigated by UV and TG.
出处
《染料与染色》
CAS
2016年第5期21-24,共4页
Dyestuffs and Coloration
基金
辽宁省科技厅自然科学基金资助项目(2014020119)
关键词
有机太阳能电池
光电特性
长碳链
硫代双烯镍
organic solar cells
photoelectric properties
long carbon chain
dithiolene nickel complexes
