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Reduction of Tb^4+ ions in luminescent Y2O3:Tb nanorods prepared by microwave hydrothermal method

Reduction of Tb^(4+) ions in luminescent Y_2O_3:Tb nanorods prepared by microwave hydrothermal method
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摘要 Terbium doped yttrium oxide was prepared with the microwave hydrothermal method. The Y2O3:Tb nanomaterial crystal- lized as needle-like grains. Bright luminescence in the green region was observed. Significant luminescence intensity increase was obtained after thermal treatment. Reduction of terbium ions was observed after heating in the air atmosphere. Tb4+ ions were found to be stabilized by crystal impurities. Hydroxyl species were found to have impact on vacancies elimination. The terbium ions were used as optical and magnetic indicator of the material properties. Terbium doped yttrium oxide was prepared with the microwave hydrothermal method. The Y2O3:Tb nanomaterial crystal- lized as needle-like grains. Bright luminescence in the green region was observed. Significant luminescence intensity increase was obtained after thermal treatment. Reduction of terbium ions was observed after heating in the air atmosphere. Tb4+ ions were found to be stabilized by crystal impurities. Hydroxyl species were found to have impact on vacancies elimination. The terbium ions were used as optical and magnetic indicator of the material properties.
出处 《Journal of Rare Earths》 SCIE EI CAS CSCD 2016年第8期774-781,共8页 稀土学报(英文版)
基金 Project supported by European Union within European Regional Development Fund,through Grant Innovative Economy(POIG.01.01.02-00-008/08)
关键词 yttrium oxide TERBIUM luminescence biomarkers abnormal reduction rare earths yttrium oxide terbium luminescence biomarkers abnormal reduction rare earths
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