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混凝对不同腐殖质生成氯代消毒副产物的影响 被引量:5

Effect of coagulation on formation of chlorinated disinfection by-products in different humic substances
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摘要 用腐殖酸1、腐殖酸2及国产富里酸三种腐殖质进行配水试验,研究了混凝对消毒副产物前体物的去除。结果表明:当聚氯化铝投加量为0-12mg/L时,混凝对腐殖酸1、腐殖酸2及国产富里酸的DOC最高去除率分别为74%、75%、18%;SUVA最高去除率分别为64%、62%、19%。混凝可选择性去除腐殖酸来源的消毒副产物前体物,如对其单位DOC的卤乙酸生成势去除率最高为53%,三卤甲烷为45%。这种选择性作用在富里酸配水体系中不显著。混凝对三种腐殖质单位DOC的水合三氯乙醛生成势基本没有影响;二氯乙腈仅来源于富里酸,混凝对其单位DOC生成势最高可降低24%。当原水中富里酸含量较高时,不适合用常规工艺控制消毒副产物生成。 No.1Humic acid,No.2humic acid,and indigenous fulvic acid were used to investigate the removal of DBPs precursors during coagulation process.When PAC dosage was between0 to 12mg/L,the optimal DOC removal rate of No.1humic acid,No.2humic acid,and indigenous fulvic acid could reach 74%,75%and 18%,respectively;as for SUVA,the highest removal rates were 64%,62% and 19%,respectively.The coagulation process could selectively remove DBPs precursors in humic acid;the highest removal rate for HAAFP/DOC was 53% and for THMFP/DOC was 45%.However,the selectivity was not obvious in the fulvic acid aqueous system.The coagulation process had little influence on CHFP/DOC of all three humic substances;DCAN was only observed in fulvic acid and the highest reduction of DCANFP/DOC was 24%.When fulvic acid proportion in source water is considerably large,the conventional process should not be adopted alone for DBPs control.
出处 《给水排水》 CSCD 北大核心 2016年第7期24-28,共5页 Water & Wastewater Engineering
基金 国家自然科学基金重大项目(51290284)
关键词 常规混凝 腐殖酸 富里酸 聚氯化铝 卤乙酸 三卤甲烷 Conventional coagulation Humic acid Fulvic acid PAC HAAs THMs
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参考文献26

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二级参考文献21

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