Underlying mechanism of the hydrothermal instability of Cu3（BTC）2 metal-organic framework 被引量：8

Underlying mechanism of the hydrothermal instability of Cu3（BTC）2 metal-organic framework

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摘要 Water induced decomposition of Cu3（BTC）2 （BTC= benzene-l,3,5-tricarboxylate） metal-organic framework （MOF） was studied using dynamic water vapour adsorption. Small-angle X-ray scattering, Fourier transform infrared spectroscopy and differential scanning calorimetry analyses revealed that the underlying mechanism of Cu3（BTC）2 MOF decomposition under humid streams is the interpenetration of water molecules into Cu-BTC coordination to displace organic linkers （BTC） from Cu centres. Water induced decomposition of Cu3（BTC）2 （BTC= benzene-l,3,5-tricarboxylate） metal-organic framework （MOF） was studied using dynamic water vapour adsorption. Small-angle X-ray scattering, Fourier transform infrared spectroscopy and differential scanning calorimetry analyses revealed that the underlying mechanism of Cu3（BTC）2 MOF decomposition under humid streams is the interpenetration of water molecules into Cu-BTC coordination to displace organic linkers （BTC） from Cu centres.

作者 Nadeen AI-Janabi Abdullatif Alfutimie Flor R. Siperstein Xiaolei Fan

机构地区 School of Chemical Engineering and Analytical Science

出处《Frontiers of Chemical Science and Engineering》 SCIE EI CAS CSCD 2016年第1期103-107,共5页 化学科学与工程前沿（英文版）

关键词 metal-organic framework （MOF） open metal sites （OMSs） dynamic water vapour adsorption hydrothermal stability metal-organic framework （MOF）, open metal sites （OMSs）, dynamic water vapour adsorption, hydrothermal stability

分类号 O641.4 [理学—物理化学] TP334.23 [理学—化学]

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参考文献20

1Zhou H C, Long J R, Yaghi O M. Introduction to metal-organic frameworks. Chemical Reviews, 2012, 112(2): 673-674. 被引量：1
2Chen Q, Chang Z, Song W C, Song H, Song H B, Hu T L, Bu X H. A controllable gate effect in cobalt(11) organic frameworks by reversible structure transformations. Angewandte Chemie Intera-tional Edition, 2013, 52(44): 11550 11553. 被引量：1
3Chui S S, Lo M F, Charmant J P, Opren A G, Williams I D. A chemically functionalizable nanoporous material [Cu3(TMA)2(- H20)3]n. Science, 1999, 283(5405): 1148-1150. 被引量：1
4Lin K S, Adhikari A K, Ku C N, Chiang C L, Kuo H. Synthesis and characterization of porous HKUST-1 metal organic frameworks for hydrogen storage. International Journal of Hydrogen Energy, 2012, 37(18): 13865- 13871. 被引量：1
5Li JR, Ma Y, McCarthy MC, Sculley J, Yu J, Jeong HK, Balbuena P B, Zhou H C. Carbon dioxide capture-related gas adsorption and separation in metal-organic frameworks. Coordina- tion Chemistry Reviews, 2011, 255(15-16): 1791-1823. 被引量：1
6Liu J, Thallapally P K, McGrail B P, Brown D R, Liu J. Progress in adsorption-based CO2 capture by metal-organic frameworks. Chemical Society Reviews, 2012, 41(6): 2308-2322. 被引量：1
7A1-Janabi N, Hill P, Torrente-Murciano L, Garforth A, Gorgojo- Alonso P, Siperstein F, Fan X. Mapping the Cu-BTC metal- organic framework (HKUST-1) stability envelope in the presence of water vapour for CO2 adsorption from flue gases. Chemical Engineering Journal, 2015, 281: 669-677. 被引量：1
8Low J J, Benin A I, Jakubczak P, Abrahamian J F, Faheem S A, Willis R R. Virtual high throughput screening confirmed experi- mentally: Porous coordination polymer hydration. Journal of the American Chemical Society, 2009, 131 (43): 15834-15842. 被引量：1
9Gul-E-Noor F, Jee B, Poeppl A, Hartmann M, Himsl D, Bertmer M. Effects of varying water adsorption on a Cu3(BTC)2 metal- organic framework (MOF) as studied by H1 and C13 solid-state NMR spectroscopy. Physical Chemistry Chemical Physics, 2011, 13 (17): 7783-7788. 被引量：1
10DeCoste J B, Peterson G W, Schindler B J, Killops K L, Browe M A, Malale J J. The effect of water adsorption on the structure of the carboxylate containing metal-organic frameworks Cu-BTC, Mg- MOF-74, and UIO-66. Journal of Materials Chemistry A, 2013, 1 (38): 11922-11932. 被引量：1

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1杨水金,王敏,杨小三.二氧化硅负载磷钨杂多酸催化合成环己酮乙二醇缩酮[J].稀有金属,2007,31(4):533-536. 被引量：15
2许招会,廖维林,王甡.磷钨酸镧催化合成缩醛(酮)的研究[J].分子催化,2008,22(1):39-43. 被引量：23
3宋绪东,贾丽华,郭祥峰.铝交联蒙脱土催化合成环己酮乙二醇缩酮[J].工业催化,2008,16(7):57-60. 被引量：7
4杨水金,李晓萍.分子筛MCM-48负载硅钨酸催化合成环己酮乙二醇缩酮[J].稀有金属,2009,33(4):573-576. 被引量：11
5章爱华,尹笃林,刘文萍,彭志远.活性炭负载对甲苯磺酸催化微波合成环己酮乙二醇缩酮[J].光谱实验室,2009,26(5):1186-1189. 被引量：11
6S. ROHANI T. ISIMJAN A. MOHAMED H. KAZEMIAN M. SALEM T. WANG.Fabrication, modification and environmental applications of TiO2 nanotube arrays （TNTAs） and nanoparticles[J].Frontiers of Chemical Science and Engineering,2012,6(1):112-122. 被引量：3
7曹小华,任杰,柳闽生,徐常龙,严平.Dawson型磷钨钼杂多酸的制备及其对H_2O_2氧化环己酮制己二酸的催化[J].应用化学,2012,29(8):915-920. 被引量：12
8杨水金,王强,段国滨,黄涛.H_4SiW_(12)O_(40)/ZrO_2-Al_2O_3催化合成丁酮1,2-丙二醇缩酮[J].徐州工程学院学报（自然科学版）,2012,27(3):22-26. 被引量：18
9邹卫华,李苛,高帅鹏,白红娟.乙二胺改性锯末对刚果红的吸附研究[J].郑州大学学报（工学版）,2013,34(2):28-31. 被引量：8
10李祥,丁斌,郝凤岭,关昶,王海东,刘群.磷钨酸掺杂聚苯胺催化合成正己酸正丁酯及其动力学研究[J].日用化学工业,2014,44(4):186-189. 被引量：8

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1向诗银,杨水金.H_6P_2Mo_9W_9O_(62)/Cu_3(BTC)_2的制备及催化合成缩醛(酮)[J].日用化学工业,2017,47(5):281-285. 被引量：2
2向诗银,杨水金.H_6P_2Mo_9W_9O_(62)/Zn(BDC)(Bipy)_(0.5)复合材料催化合成3,4-二氢嘧啶-2(H)酮衍生物[J].化学试剂,2017,39(10):1039-1043.
3赵巢圣,常薇,杜燕萍,刘斌,张毛进.Cu-BTC-SiO_2材料的制备及其对亚甲基蓝的吸附性能[J].纺织高校基础科学学报,2017,30(4):547-552. 被引量：3
4Kasra Pirzadeh,Ali Asghar Ghoreyshi,Mostafa Rahimnejad,Maedeh Mohammadi.Optimization of electrochemically synthesized Cu3(BTC)2 by Taguchi method for CO2/N2 separation and data validation through artificial neural network modeling[J].Frontiers of Chemical Science and Engineering,2020,14(2):233-247. 被引量：1
5Ehsan Rahmani,Mohammad Rahmani.Catalytic process modeling and sensitivity analysis of alkylation of benzene with ethanol over MIL-101(Fe) and MIL-88(Fe)[J].Frontiers of Chemical Science and Engineering,2020,14(6):1100-1111. 被引量：4
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8郭翔宇,李森.水稳定功能化Cu-BTC基混合基质膜的制备及其CO_(2)分离应用[J].天津工业大学学报,2024,43(1):10-16.

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1向诗银,李志鹏,杨水金.SBA-15复合材料的制备及其催化合成环己酮乙二醇缩酮[J].日用化学工业,2017,47(11):641-644. 被引量：3
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5Zaiku Xie,Bao-Lian Su.Crystalline porous materials:from zeolites to metal-organic frameworks(MOFs)[J].Frontiers of Chemical Science and Engineering,2020,14(2):123-126.
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8Ya Li,Wei Ling,Xinyu Liu,Xue Shang,Pan Zhou,Zhaorun Chen,Hang Xu,Xian Huang.Metal-organic frameworks as functional materials for implantable flexible biochemical sensors[J].Nano Research,2021,14(9):2981-3009. 被引量：4
9武国蓉,樊强文,孙文杰,汪涛,任绘君,朱海波,罗屹东.Cd_(2)(bcbpy)_(0.5)Cl_(4)的晶体结构与光致变色性能研究[J].东华理工大学学报（自然科学版）,2022,45(1):96-100.
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1顾明松,罗毅.毛细管气相色谱法测定热不稳定有机磷农药辛硫磷[J].色谱,1995,13(6):470-471. 被引量：16
2王少芬,魏建谟.超临界流体色谱在金属络合物和金属有机化合物中的分析应用[J].分析化学,2001,29(6):725-730. 被引量：13
3李旭,蔡瑞芳,孔庆宇,赵利,李郁芬,俞宏坤,侯健,侯惠奇.C_60的氧化反应研究[J].高等学校化学学报,2001,22(4):515-519. 被引量：3
4产品开发[J].广州化工,2015,43(15):256-256.
5王方方,魏鹏月,丁学勇,邢献然,陈星秋.Towards a Mechanism Underlying the Stability of the Tetragonal CuO Phase： Comparison with NiO and CoO by Hybrid Density Functional Calculation[J].Chinese Physics Letters,2014,31(2):109-112.
6邓林,倪基华,陈鉴清.质谱─质谱技术直接分析热不稳定混合物[J].质谱学报,1995,16(1):73-76.
7魏先文,徐正.电喷雾电离质谱在化学中应用新进展[J].有机化学,1999,19(1):97-103. 被引量：16
8魏先文,锁志勇,徐正.电喷雾电离质谱在富勒烯化学中的应用进展[J].化学通报,1998(8):5-11. 被引量：4
9汪正范,曹红.用DEI-MS分析某些硝基化合物[J].分析测试通报,1992,11(6):84-86. 被引量：1
10Bin Li,Banglin Chen.A flexible metal-organic framework with double interpenetration for highly selective CO2 capture at room temperature[J].Science China Chemistry,2016,59(8):965-969. 被引量：4

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Underlying mechanism of the hydrothermal instability of Cu3（BTC）2 metal-organic framework 被引量：8

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