摘要
Chemical looping combustion is a promising technology for energy conversion due to its low-carbon, high-efficiency, and environmental-friendly feature. A vital issue for CLC process is the development of oxygen carrier, since it must have sufficient reactivity. The mechanism and kinetics of CO reduction on iron-based oxygen carriers namely pure Fe2O3 and Fe2O3 supported by alumina （Fe2O3/Al2O3） were investigated using thermo-gravimetric analysis. Fe2O3/Al2O3 showed better reactivity over bare Fe2O3 toward CO reduction. This was well supported by the observed higher rate constant for FezO3/Al2O3 over pure Fe2O3 with respective activation energy of 41.1±2.0 and 33.3±0.8 kJ. mol^-1. The proposed models were compared via statistical approach comprising Akaike information criterion with correction coupled with F-test. The phase-boundary reaction and diffusion control models approximated to 95% confidence level along with scanning electron microscopy results; revealed the promis- ing reduction reactions of pure Fe203 and Fe2O3/Al2O3. The boosting recital of iron-based oxygen carrier support toward efficient chemical looping combustion could be explained accurately through the present study.
Chemical looping combustion is a promising technology for energy conversion due to its low-carbon, high-efficiency, and environmental-friendly feature. A vital issue for CLC process is the development of oxygen carrier, since it must have sufficient reactivity. The mechanism and kinetics of CO reduction on iron-based oxygen carriers namely pure Fe2O3 and Fe2O3 supported by alumina （Fe2O3/Al2O3） were investigated using thermo-gravimetric analysis. Fe2O3/Al2O3 showed better reactivity over bare Fe2O3 toward CO reduction. This was well supported by the observed higher rate constant for FezO3/Al2O3 over pure Fe2O3 with respective activation energy of 41.1±2.0 and 33.3±0.8 kJ. mol^-1. The proposed models were compared via statistical approach comprising Akaike information criterion with correction coupled with F-test. The phase-boundary reaction and diffusion control models approximated to 95% confidence level along with scanning electron microscopy results; revealed the promis- ing reduction reactions of pure Fe203 and Fe2O3/Al2O3. The boosting recital of iron-based oxygen carrier support toward efficient chemical looping combustion could be explained accurately through the present study.
