摘要
选取我国中亚热带典型的常绿阔叶林米槠天然林(Castanopsis carlesii)为研究对象,采集林内米槠凋落物并通过挖剖面法分6个土层采集土样至1m。通过浸提米槠凋落物得到可溶性有机碳(dissolved organic carbon,DOC)溶液并在室内模拟其在不同土层的淋溶过程,不仅分析了土壤性质对DOC淋溶的影响,还研究了淋溶前后DOC化学结构的变化,以阐明DOC在不同土层中的迁移特征及影响因素,探寻米槠天然林土壤的固碳潜力和DOC在土壤有机碳循环中的作用。结果表明:(1)下层土壤比上层土壤吸附DOC的能力更强,亲水性DOC与疏水性DOC间会争夺土壤颗粒表面的吸附位点,而且芳香化合物和大分子物质等疏水性DOC组分会被优先吸附;(2)红外光谱表明,芳香类和醚类等疏水性物质会优先被吸附,烷烃类物质却不易被吸附,土壤中原有的酚、醇类亲水性物质会被初始DOC中的疏水性物质置换出来;(3)土壤DOC的截留能力与粘粒、游离氧化铁含量呈极显著正相关,而与土壤有机碳和砂粒含量呈极显著负相关,其中土壤有机碳的含量是影响米槠天然林不同土层DOC截留量的关键因素。
Dissolved organic carbon （DOC） is a mixture of organic compounds with varying molecular sizes and weights. In forest ecosystems, litterfall is a major aboveground resource of DOC, which supplies soils with carbon as a crucial component of terrestrial biogeochemical cycles. During the migration of litterfall-derived DOC from topsoils to subsoils, soils might retain, transform, or release DOC, depending on the chemical nature of DOC and its interactions with soil surfaces. These physicochemical processes contribute considerably to soil organic carbon （SOC） accumulation. It is accepted generally that soil properties have a great influence on the interaction between soil surface and DOC, with Fe/A1 oxides constraining DOC losses and high SOC content being usually negatively correlated to DOC sorption. However, an inconsistency still remains regarding the extent to which soils properties impact DOC movement. In some cases topsoils rich in SOC might demonstrate higher DOC retention capacity. Although subsoils with abundant Fe/AI oxides are considered to have a stronger DOC retention capacity, relatively lower SOC content is often found in subsoils, and direct evidence for their higher carbon sequestration potential is rare. One reason for this maybe the amount of DOC from aboveground litterfa11, which is not sufficient and little DOC can reach subsoils. Another reason might be that highly sorptive DOC is preferentially absorbed by topsoils, and DOC that reaches subsoils has a weak affinity for soil surfaces. Supplying individual soil horizons with a common DOC solution is thus a good way to differentiate their carbon sequestration capacities. Natural Castanopsis carlesii forests are dominant evergreen broad-leaf forests in mid-subtropical China, and interaction between litterfall derived DOC and red soil （Ferralic Cambisols, World Reference Base） is now recognized as one of the most important mechanisms of C sequestration in this region. To solve inconsistencies about factors controlling DOC translocation i
出处
《生态学报》
CAS
CSCD
北大核心
2015年第17期5711-5720,共10页
Acta Ecologica Sinica
基金
国家自然科学青年基金项目(31100467)
福建师范大学优秀青年骨干教师培养基金(fjsdky2012008)
国家自然科学基金重点项目(31130013)
福建省自然科学青年基金项目(2011J05105)
高等学校博士学科点专项科研基金(优先发展领域)(20113503130001)
关键词
可溶性有机碳(DOC)
淋溶
吸附
光谱分析
dissolved organic carbon （DOC）
leaching
adsorption
spectral analysis
