摘要
Two novel metal-organic coordination compounds with molecular structures of {[Co（TMBC）4Cl2]·2H2O}（1） and {[Ni（TMBC）4Cl2]·2H2O}（2）（TMBC = 4＇-（（1H-1,2,4-triazol-1-yl）methyl）-[1,1＇-biphenyl]-2-carbonitrile）, have been synthesized under hydrothermal conditions of Co Cl2·6H2O and Ni Cl2·6H2O with 4＇-（（1H-1,2,4-triazol-1-yl）methyl）-[1,1＇-biphenyl]-2-carbonitrile, respectively. Both compounds crystallize in triclinic systems, space group P 1. They are characterized by single-crystal X-ray diffraction analysis, elemental analysis, IR spectroscopy and TGA. Moreover, their electrochemical behaviors have also been studied in different electrolyte solutions, respectively.
Two novel metal-organic coordination compounds with molecular structures of {[Co（TMBC）4Cl2]·2H2O}（1） and {[Ni（TMBC）4Cl2]·2H2O}（2）（TMBC = 4＇-（（1H-1,2,4-triazol-1-yl）methyl）-[1,1＇-biphenyl]-2-carbonitrile）, have been synthesized under hydrothermal conditions of Co Cl2·6H2O and Ni Cl2·6H2O with 4＇-（（1H-1,2,4-triazol-1-yl）methyl）-[1,1＇-biphenyl]-2-carbonitrile, respectively. Both compounds crystallize in triclinic systems, space group P 1. They are characterized by single-crystal X-ray diffraction analysis, elemental analysis, IR spectroscopy and TGA. Moreover, their electrochemical behaviors have also been studied in different electrolyte solutions, respectively.
基金
Supported by the National Natural Science Foundation of China(No.21201087)
NSF of Jiangsu Province(BK20131244 and BK20130460)
the Foundation of Jiangsu Educational Committee(11KJB150004)
the Qing Lan Project of Jiangsu Province and Jiangsu Overseas Research&Training Program for University Prominent Young&Middle-aged Teacher and Presidents,the Innovation Program of Graduate Students in Jiangsu Province(SJZZ-0142)
