摘要
Under hydrothermal conditions, 4-（4,5-dicarboxy-lH-imidazol-2-yl）pyridine 1-oxide （H3DCImPyO） reacted with ZnC12 to give the 1D chain complex {[Zn（DCImPyO）·（H2O）2·]·H3O}n （1）. Single-crystal X-ray determination shows that complex 1 crystallizes in the monoclinic system, space group P21/c with a = 9.488（2）, b = 13.247（3）, c = 12.959（4） A, β = 126.716（19）°, Z = 4, V= 1305.6（6）/k3, C10H11N3O8Zn, Dc = 1.865 g/cm3, Mr = 366.61, 2（MoKa） = 0.71073 A, μ= 1.930 mm1, F（000） = 744, R = 0.0472 and wR = 0.1487. Fluorescent analysis showed an intense emission band at 422 nm when the exciting radiation was set at 378 nm. Dielectric constant of complex 1 was measured at different frequencies with temperature variation.
Under hydrothermal conditions, 4-（4,5-dicarboxy-lH-imidazol-2-yl）pyridine 1-oxide （H3DCImPyO） reacted with ZnC12 to give the 1D chain complex {[Zn（DCImPyO）·（H2O）2·]·H3O}n （1）. Single-crystal X-ray determination shows that complex 1 crystallizes in the monoclinic system, space group P21/c with a = 9.488（2）, b = 13.247（3）, c = 12.959（4） A, β = 126.716（19）°, Z = 4, V= 1305.6（6）/k3, C10H11N3O8Zn, Dc = 1.865 g/cm3, Mr = 366.61, 2（MoKa） = 0.71073 A, μ= 1.930 mm1, F（000） = 744, R = 0.0472 and wR = 0.1487. Fluorescent analysis showed an intense emission band at 422 nm when the exciting radiation was set at 378 nm. Dielectric constant of complex 1 was measured at different frequencies with temperature variation.
基金
Supported by the Natural Science Foundation of Jiangsu Province(BK2008029)
the Foundation of Jiangsu Educational Committee(11KJB150004)
