摘要
用含氮配体Mdcp和柔性的二元羧酸戊二酸为混合配体合成了一个新型的镉配合物[Cd(Mdcp)(GTC)]n(1),并且通过元素分析、热失重分析、红外和X-射线单晶衍射对配合物(1)进行了表征,结构表明此配合物为新颖的二维层状结构,并且通过氢键作用形成三维的网状结构,热失重曲线清晰的表明了各个温度区间内的失重情况.此外研究了配合物(1)的荧光发光性质.
A novel metal-organic coordination compound [ Cd（ Mdcp ）（ GTC ）]n（ 1 ）[ Mdcp = 2-（ 3-methoxyphenyl）-1H-imidazo[4,5-f][1,10]phenanthroline,GTC = pentanedioic acid]has been synthesized by hydrothermal reactions and characterized by elemental analysis,thermogravimetric（ TG） analysis,infrared spectrum（ IR）and single-crystal X-ray diffraction. The single-crystal X-ray diffraction result reveals that the compound（1）exhibits two-dimensional（2D）layer architecture which is linking to 3D structure by the H-bond intersections. The TG analysis result shows the courses of weight loss. We also study the luminescent properties of the compound（1）.
出处
《吉林师范大学学报（自然科学版）》
2014年第4期15-18,共4页
Journal of Jilin Normal University:Natural Science Edition
基金
吉林省科技发展计划项目(20060571
20120440)
关键词
镉
晶体结构
热失重分析
荧光
cadmium
crystal structures
thermal stability analysis
fluorescence
