摘要
Cu(TO)2(H2O)4](PA)2 was prepared by mixing the aqueous solution of 1,2,4 triazol 5 one(TO) and Cu(PA)2. The molecular structure and crystal structure of the title complex was determined by X ray single crystal diffraction method. The crystal is triclinic, space group with a=0.7321(1)nm,b=0.7474(2)nm,c=1.3649(3)nm;α=88.65(2)°,β=85.63(1)°,γ=63.35(1)°;V=0.6655(2)nm3,Z=1. The Cu2+ coordinated with two TO molecule through its 2 nitrogen atom and four water molecules and showed an octahedral configuration.
[Cu (TO)(2) (H2O)(4)](PA)(2) was prepared by mixing the aqueous solution of 1, 2, 4-triazol-5-one (TO) and Cu(PA)(2). The molecular structure and crystal structure of the title complex was determined by X-ray single crystal diffraction method. The crystal is triclinic, space group with a = 0. 7321 (1) rim, b = 0. 7474 (2) nm, c = 1. 3649 (3) nm; alpha = 88. 65 (2)degrees beta = 85.63 (1)degrees, gamma = 63. 35 (1)degrees; V = 0. 6655 (2) nm(3), Z = 1. The Cu2+ coordinated with two TO molecule through its 2-nitrogen atom and four water molecules and showed an octahedral configuration.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2002年第3期284-288,共5页
Chinese Journal of Inorganic Chemistry
