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TiO_2纳米粒子的光催化活性与光伏响应特性研究 被引量:20

Researches on Photocatalytic Activities and Photovoltaic Properties of TiO_2 Nanoparticles
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摘要 We investigated the photovoltaic properties of series of TiO 2 photocatalysts by means of SPS and found that the thresholds of TiO 2 particles blue shift with their particle sizes decreasing and crystal phases changing from rutile TiO 2 to anatase TiO 2. Combining with the photodegradation activities of TiO 2 on C 7H 16 , it was concluded that the photocatalytic activities of TiO 2 increase with their thresholds increasing,which can be explained using energy band theory. We also investigated the relationship beween the photovoltaic properties and photocatalytic activities of B TiO 2 before and after photooxidation on C 7H 16 , SO 2 and C 7H 16 +SO 2, respectively and found adsorbates at the surface of TiO 2 affect their photocatalytic activities and conduction types of surface layer. We investigated the photovoltaic properties of series of TiO 2 photocatalysts by means of SPS and found that the thresholds of TiO 2 particles blue shift with their particle sizes decreasing and crystal phases changing from rutile TiO 2 to anatase TiO 2. Combining with the photodegradation activities of TiO 2 on C 7H 16 , it was concluded that the photocatalytic activities of TiO 2 increase with their thresholds increasing,which can be explained using energy band theory. We also investigated the relationship beween the photovoltaic properties and photocatalytic activities of B TiO 2 before and after photooxidation on C 7H 16 , SO 2 and C 7H 16 +SO 2, respectively and found adsorbates at the surface of TiO 2 affect their photocatalytic activities and conduction types of surface layer.
出处 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 2001年第5期827-829,共3页 Chemical Journal of Chinese Universities
基金 国家自然科学基金 (批准号 :2 99710 13 ) 吉林省科委资助
关键词 表面光电压谱 二氧化钛纳米粒子 光催化活性 光催化剂 光伏响应 TiO 2 Photocatalysis SPS Photodegradation
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二级参考文献2

  • 1王宝辉,Chin Chem Lett,1994年,5卷,627页 被引量:1
  • 2王德军,化学通报,1989年,10卷,32页 被引量:1

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