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氢处理二氧化钛的光催化性能及电化学阻抗谱 被引量:28

Photocatalytic Activity and Electrochemical Impedance Spectroscopy of TiO_2 Thermally Treated by Hydrogen
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摘要 TiO2 treated in hydrogen atmosphere showed enhanced photocatalytic activity in degrading the sulfosalicylic acid (SSal).The results of the electrochemical impedance spectroscopy (EIS) investigation showed that the diameters of the capacitive arcs for the H-TiO2 were much smaller than those of bare TiO2 and thermally treated TiO2 in air,indicating that the charge transfer of the H-TiO2 occurs more rapidly,thus inviting a higher photocatalytic activity.When an external bias was applied on the H-TiO2,the arc of the EIS Nyquist plot decreased obviously than without the bias,suggesting more efficient separation of the photo-generated carriers. TiO2 treated in hydrogen atmosphere showed enhanced photocatalytic activity in degrading the sulfosalicylic acid (SSal),The results of the electrochemical impedance spectroscopy (EIS) investigation showed that the diameters of the capacitive arcs for the H-TiO2 were much smaller than those of bare TiO2 and thermally treated TiO2 in air, indicating that the charge transfer of the H-TiO2 occurs more rapidly, thus inviting a higher photocatalytic activity. when an external bias was applied on the H-TiO2, the arc of the EIS Nyquist plot decreased obviously than without the bias, suggesting more efficient separation of the photo-generated carriers.
出处 《物理化学学报》 SCIE CAS CSCD 北大核心 2001年第3期286-288,共3页 Acta Physico-Chimica Sinica
基金 中国科学院重大项目!(KJ951-A1-505) 国家博士后基金资助项目
关键词 光催化 二氧化钛 电化学阻抗谱 氢处理 催化剂 改性 催化活性 photocatalysis titanium dioxide electrochemical impedance spectroscopy
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