摘要
以3-羟基-1-金刚烷甲醇和乙炔为原料,庚烷为溶剂,叔丁醇钾为催化剂,氧化锌为助催化剂,于140℃/1.0 MPa反应3.0 h合成了3-羟基-1-金刚烷甲基乙烯基醚,收率85%,纯度≥99.5%,其结构经IR确证。
3-Hydroxy-1-adamantane methyl vinyl ether in yield of 85％ with ≥99.5％ purity was synthesized by the reaction of 3-hydroxy-1-adamantane methanol with acetylene using potassium tertbutyl alcohol as the catalyst,zinc oxide as the cocatalyst and heptane as the solvent at 140 ℃/1.0 MPa for 3.0 h.The structure was confirmed by IR.
出处
《合成化学》
CAS
CSCD
北大核心
2013年第5期623-626,共4页
Chinese Journal of Synthetic Chemistry
