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Effect of Y_2O_3 on the crystallization kinetics of TiO_2 nucleated LAS glass for the production of nanocrystalline transparent glass ceramics 被引量:2

Effect of Y_2O_3 on the crystallization kinetics of TiO_2 nucleated LAS glass for the production of nanocrystalline transparent glass ceramics
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摘要 Crystallization kinetics of metastable B-quartz solid solution as a desirable phase for the production of trans- parent lithium aluminosilicate (LAS) glass ceramics was investigated in the presence of Y203. Accordingly, differential thermal analysis scans were performed thoroughly to study the mechanism of crystallization kinetics. The aim of this investigation is to discover the complicated mechanism of crystallization process in the presence of co-additives and ac- cordingly find a way for increasing the transparency of glass ceramics. It is shown that the bulk (3D) growth is intensively increased by the enhancement of Y203. Then again, reducing nucleation and increasing growth mechanisms were recog- nized for the LAS system in the presence of Y2O3. Results of the investigation illustrate that when co-additives are added to glasses, it is necessary to nucleate the optical component separately before the growth process. Crystallization kinetics of metastable B-quartz solid solution as a desirable phase for the production of trans- parent lithium aluminosilicate (LAS) glass ceramics was investigated in the presence of Y203. Accordingly, differential thermal analysis scans were performed thoroughly to study the mechanism of crystallization kinetics. The aim of this investigation is to discover the complicated mechanism of crystallization process in the presence of co-additives and ac- cordingly find a way for increasing the transparency of glass ceramics. It is shown that the bulk (3D) growth is intensively increased by the enhancement of Y203. Then again, reducing nucleation and increasing growth mechanisms were recog- nized for the LAS system in the presence of Y2O3. Results of the investigation illustrate that when co-additives are added to glasses, it is necessary to nucleate the optical component separately before the growth process.
出处 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2013年第5期450-455,共6页 矿物冶金与材料学报(英文版)
关键词 glass ceramics lithium aluminosilicate YTTRIA crystallization kinetics NANOCRYSTALS TRANSPARENCY glass ceramics lithium aluminosilicate yttria crystallization kinetics nanocrystals transparency
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