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Stereoselective Synthesis of (-)-Chloramphenicol, (+)-Thiamphenicol and (+)-Sphinganine via Chiral Tricyclic Iminolactone 被引量:2

Stereoselective Synthesis of (-)-Chloramphenicol, (+)-Thiamphenicol and (+)-Sphinganine via Chiral Tricyclic Iminolactone
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摘要 The stereoselective syntheses of (-)-chloramphenicol, (+)-thiamphenicol and (+)-sphinganine are described. The two continuous chiral centers within three target molecules were constructed through aldol reaction of chiral tricyclic iminolactone and aldehyde. The stereoselective syntheses of (-)-chloramphenicol, (+)-thiamphenicol and (+)-sphinganine are described. The two continuous chiral centers within three target molecules were constructed through aldol reaction of chiral tricyclic iminolactone and aldehyde.
出处 《Chinese Journal of Chemistry》 SCIE CAS CSCD 2013年第1期149-153,共5页 中国化学(英文版)
基金 Acknowledgement We are grateful for the National Basic Research Program of China (No. 2011CB833200), the National Natural Science Foundation of China (Nos. 20772051, 20972058), the "111" Program from MOE of P. R. China and the Fundamental Research Funds for the Central Universities (lzujbky-2012-90).
关键词 β-hydroxy-a-amino alcohol tricyclic iminolactone total synthesis β-hydroxy-a-amino alcohol, tricyclic iminolactone, total synthesis
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