摘要
以乙醛酸和亚磷酸二乙酯为原料,合成α-羟基膦酸酯化合物,进一步羟基保护,羧基保护,合成了丹参素衍生物的中间体2-酰氧基-2-(二乙氧基膦酰基)乙酸甲酯,并用IR,1H谱,13C谱对化合物进行了表征.
This research focused on a series of α- hydroxyl phosphonate synthesis by using the raw materials glyox- ylate and diethyl phosphite, and with further carboxyl protection and hydroxyl protection, it synthesized the deriva- tive intermediate of danshengsu Methyl 2 - acyloxy - 2 - （ diethoxy phosphoryl ） acetate. The product was char-acterized by IR, 1H NMR and 13C NMR.
出处
《云南民族大学学报（自然科学版）》
CAS
2013年第2期91-92,98,共3页
Journal of Yunnan Minzu University:Natural Sciences Edition
基金
云南省自然科学基金(2008CD197)
