摘要
首次报道了新型Schiff碱配合物-双[N,N’-亚乙基-2,2’-(苯亚甲基)二(3,4-二甲基吡咯-5-醛缩亚胺)]合单金属配合物MH_2L[M=Mn(Ⅱ)、Fe(Ⅲ)Cl、Cr(Ⅲ)Cl、Cu(Ⅱ)、Co(Ⅱ)、Ni(Ⅱ)、Zn(Ⅱ)]的合成方法及光谱特征。
The syntheses of bis[TV, N' - ethylene - 2,2' - (phenylmethylene)bis(3,4 - dimethyl pyrrole - 5 -aldimino) ]monometallic complexes MH2L [M = Mn( II ) , Fe( III ) Cl, Cr(III) Cl, Cu( II ), Co( II ) , Ni( II ) , Zn ( II ) ] were first described . Their spectral characters and configurations were also discussed . The monometallic complexes were prepared by the reaction of ethylenediamine with another series of Schiff base mononuclear complexes, derived by the reaction of the appropriate metal salts with a Schiff base ligand. The Schiff base ligand was prepared from the [l + 2] condensation of ethylenediamine with 2,2'- (phenylmethylene)bis(3, 4 - dimethylpyrrole - 5 - carbox-aldehyde) .
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
2000年第4期547-550,共4页
Chinese Journal of Organic Chemistry
基金
国家自然科学基金
