摘要
以三聚氯氰、Na2S和NaOH为起始原料,在pH值5～8的条件下,得到了2,4,6-三巯基均三嗪单钠盐的晶体,并对其进行了红外光谱、元素分析测试及单晶结构表征.晶体学参数为:单斜晶系,P2(1)/c空间群,a=10.479(4),b=12.761(5),c=7.822(3),β=109.623(6)°,V=992.8(7)3,Z=4,Dc=1.695 g.cm-3,R1=0.044 4,wR2=0.136 0(I>2σ),GOF=1.128.
The monosodium salt of 2,4,6-trimercapto-s-triazine Na(H2O)3C3H2N3S3 was synthesized by the reaction of C3N3Cl3 with Na2S and NaOH in the solution of pH=5～8,and it is characterized by IR spectrum and element analysis.Its structure is determined by X-ray diffraction analysis.The salt crystallizes in the monoclinic space group P2(1)/c with a=10.479(4),b=12.761(5),c=7.822(3),β=109.623(6)°,V=992.8(7).3,Z=4,Dc=1.695 g·cm-3,R1=0.044 4,wR2=0.136 0(I>2),GOF=1.128.
出处
《西安石油大学学报（自然科学版）》
CAS
北大核心
2012年第5期86-89,11,共4页
Journal of Xi’an Shiyou University（Natural Science Edition）
基金
陕西省教育厅专项基金项目(编号:2010JK782)
关键词
2
4
6-三巯基均三嗪单钠盐
合成
晶体结构
2,4,6-trimercapto-s-triazine monosodium salt
synthesis
crystallographic structure
