摘要
通过自由基聚合的方法制备了一系列甲基丙烯酸甲酯和C60的共聚物,实验结果表明,增加引发剂的含量可以大大提高共聚物的产率.用元素分析、GPC和DSC等方法对共聚物进行表征.首次尝试研究了不含导电高分子的C60共聚物体系的光电导性能,结果表明,该类共聚物光电导性能良好.
A series of C60/MMA copolymers were synthesized by free radical polymerization. The experimental results showed that the polymerization conversion rate went up along with Increasing the amount of initiator dramatically. Meanwhile, the C60/MMA copolymers were characterized by the techniques of elemental analysis, GPC and DSC. In this paper, the photoconductivity of the C60/MMA copolymers was al- so studied, and the influence parameters, such as exposure intensity, thickness of interface layer, of the photoconductivity have been discussed, separately. From the experimental results, it can be conclude that C60/MMA copolymers will become a candidate of photoelectric materials.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
2000年第5期805-808,共4页
Chemical Journal of Chinese Universities
基金
国家自然科学基金青年基金!(批准号:59703004)