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Influence of Ga and Bi on electrochemical performance of Al-Zn-Sn sacrificial anodes 被引量:9

Ga和Bi对Al-Zn-Sn牺牲阳极电化学性能的影响(英文)
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摘要 The influence of Ga and Bi on the microstructure and electrochemical performance of Al-7Zn-0.1Sn (mass fraction,%) sacrificial anodes was investigated by means of optical microscopy (OM),scanning electron microscopy/energy dispersive X-ray analysis (SEM/EDAX) and electrochemical measurements.It was found that the coarse dendrites structure transformed into the equiaxed grains as well as a small amount of dendrite grains after adding Ga and Bi into Al-Zn-Sn alloys.A high current efficiency of 97% and even corrosion morphology were obtained for Al-7Zn-0.1Sn-0.015Ga-0.1Bi alloy.The results indicate that the proper amount of Ga and Bi is effective on improving the microstructure and electrochemical performance of Al-Zn-Sn alloy. 通过光学显微镜(OM)、扫描电镜(SEM)、能谱分析(EDAX)和电化学性能测试等方法,研究了Ga和Bi对Al-7Zn-0.1Sn(质量分数,%)牺牲阳极微观组织和电化学性能的影响。Al-Zn-Sn合金加入Ga和Bi元素后,合金组织由粗大枝晶转变为等轴晶,仅剩下少量枝晶。Al-7Zn-0.1Sn-0.015Ga-0.1Bi合金具有高的电流效率(97%)和均匀的腐蚀形貌,表明添加适量的Ga和Bi元素能有效改善Al-Zn-Sn合金的组织和电化学性能。
出处 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2011年第7期1580-1586,共7页 中国有色金属学报(英文版)
基金 Project(094200510019) supported by Technology Creative Programmer of Henan for Excellent Talents,China Project(092300410132) supported by the Natural Science Foundation of Henan Province,China
关键词 aluminium sacrificial anode electrochemical performance electrochemical impedance spectroscopy SEGREGATION 牺牲阳极 电化学性能 电化学阻抗谱 偏析
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