摘要
文献中研究了1,1-二氰乙烯基-2,2-二硫醇盐(简称i-mnt)的Cu(Ⅱ)和 Ni(Ⅱ)配合物.现合成出i-mnt的钒(Ⅳ)和铁(Ⅲ)配合物,根据钒(Ⅳ)配合物的ESR谱和铁(Ⅲ)配合物的Mossbauer谱及其他光谱探讨它们的键合和结构。
Fe(III) and V(IV) coordination compounds containing 1,1-cyanoethylene-2,2-dithiolate (abbr. as i-mnt) were synthesized. They were characterized by elemental analyses, magnetic susceptibilities, infrared spectra and UV-spectra measurements. Fe(III) and V(IV) complexes were researched by Mossbauer spectrum and ESR spectrum respectively. The results indicated that Fe(III) complex is dimeric, and V(IV) complex is monomeric.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
1990年第3期347-349,共3页
Chinese Journal of Inorganic Chemistry
关键词
钒配合物
铁配合物
二硫醇盐
2,2-dithlolate vanadism(IV)eomplex Iron(III)complex
