摘要
在超声波辐射下,以活性炭负载浓硫酸作催化剂,催化合成了β-萘甲醚。考察了超声波辐射功率、辐射时间、无水甲醇用量、催化剂用量等因素对合成工艺的影响。确定了最佳反应条件:n(β-萘酚)∶n(无水甲醇)=1∶6,x(催化剂)=7%,超声波辐射功率200W,反应时间为15min,反应温度为80℃,在该条件下,β-萘甲醚产率为98.3%。该方法条件温和、操作简便高效。
β-Naphthyl methyl ether was synthesized in the presence of a new kind of the cheap and effective environmental friendly solid catalyst H2SO4/Carbon under the ultrasonic irradiation.The influences of catalyst＇s dosage,methanol consumption,reaction time and ultrasonic power on the yield of product have been investigated.The optimal reaction conditions are as follow：the mole ratio of β-naphthol and methanol is 1：6,catalyst molar fraction is 7%,ultrasonic power is 200 W,reaction time is 15 min and temperature is 80 ℃.Under the optimal reaction condition,the yield of β-naphthyl methyl ether is 98.3%.The reaction condition is mild.The method is simple and efficient.
出处
《精细化工》
EI
CAS
CSCD
北大核心
2010年第10期1038-1040,共3页
Fine Chemicals
基金
国家自然科学基金(20562010
20962016)
宁夏自然科学基金(NZ1006)
教育部"新世纪优秀人才支持计划资助"资助项目(NCET-09 -0860)~~
关键词
超声波
改性活性炭
无溶剂合成
β-萘甲醚
精细化工中间体
ultrasonic irradiation
modified activated carbon
solvent-free synthesis
β-naphthyl methyl ether
fine chemical intermediates
