摘要
合成了S-甲基二硫代肼基甲酸的西夫碱双铜配合物并用各种物理方法对其进行了结构鉴定。生物试验表明配合物对各类微生物具有一定抑制作用。用循环伏安法研究了经双铜配合物修饰的双层脂膜(bilayer lipid membrane,BLM)上的氧化还原反应,表明配合物在膜内起电子递体的作用。
A bicopper (Ⅱ) complex Cu_2L_2Cl_2 with S-methyldithiocarbazate ligand was synthesized and characterized by various physical methods. It has been found that the complex has an activity of inhibition against some moulds bacteria and yeasts. Redox reactions on bilayer lipid membrane (BLM) modified by Cu_2L_2Cl_2 was investigated by cyclic voltammetry method and the action of electron carrier of this complex on BLM was reported.
出处
《生物化学与生物物理进展》
SCIE
CAS
CSCD
北大核心
1990年第4期281-285,共5页
Progress In Biochemistry and Biophysics
基金
国家自然科学基金
关键词
西夫碱
铜
活性
双层脂膜
电子传递
hydrazinecarbodithioic acid, Schiff bases, copper activity, cyclic voltammetry, membrane, electrode reaction
