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钙系化合物对镍电极的作用 被引量:1

The Effect of Calcium Compounds on Nickel Electrodes
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摘要 镍电极在充电过程中由于析氧而使充电效率不高,添加钙化合物可以提高析氧过电位从而抑制氧气的析出,添加钴可以增加活性物质在放电过程中的导电性且有利于活性物质的转化反应,同时添加钴和钙可以显著提高活性物质的利用率和放电电位。 Nickel hydroxide electrode normally exhibits a poor charge acceptance resulting from the competitive reactions of the oxidation of active material and the evolution of oxygen.The addition of cobalt and calcium compound together to the nickel hydroxide can improve remarkably the utilization and discharge potential of active material,where the action of calcium additive is to increase the oxygen evolution potential,while the effects of cobalt is attributable to a good conductivity of the active material both for electrons and protons.
机构地区 浙江大学化学系
出处 《功能材料》 EI CAS CSCD 北大核心 1999年第3期276-278,共3页 Journal of Functional Materials
基金 国家863计划项目 浙江省自然科学基金
关键词 钙化合物 添加剂 镍电极 碱性电池 calcium compound cobalt additive nickel electrode effect
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  • 1K. Watanabe,T. Kikuoka,N. Kumagai. Physical and electrochemical characteristics of nickel hydroxide as a positive material for rechargeable alkaline batteries[J] 1995,Journal of Applied Electrochemistry(3):219~226 被引量:1
  • 2M. Keddam,S. Senyarich,H. Takenouti,P. Bernard. A composite electrode for studying powdered electroactive materials: preparation and performance[J] 1994,Journal of Applied Electrochemistry(10):1037~1043 被引量:1
  • 3R. D. Armstrong,G. W. D. Briggs,E. A. Charles. Some effects of the addition of cobalt to the nickel hydroxide electrode[J] 1988,Journal of Applied Electrochemistry(2):215~219 被引量:1
  • 4Masahiko Oshitani,Takashi Takayama,Koichiro Takashima,Shigeo Tsuji. A study on the swelling of a sintered nickel hydroxide electrode[J] 1986,Journal of Applied Electrochemistry(3):403~412 被引量:1
  • 5Anil K. Sood. Studies on the effect of cobalt addition to the nickel hydroxide electrode[J] 1986,Journal of Applied Electrochemistry(2):274~280 被引量:1
  • 6杨华铨,张静芳,杨文治.粉体MnO_2电极的循环伏安研究[J].北京大学学报(自然科学版),1992,28(6):683-690. 被引量:6

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