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桉木硫酸盐浆DMD漂白工艺条件的研究 被引量:2

The Study on DMD Bleaching Conditions of Eucalyptus Kraft Pulp
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摘要 使用新漂剂二甲基二环氧乙烷漂白桉木硫酸盐浆时,应严格控制反应的pH值为7.0-7.5,过氧硫酸盐和丙酮用量增加,二甲基二环氧乙烷的漂白能力随这增强;5%用量的DMD漂浆经碱抽提后脱木素与氧脱木素相当,但前者漂浆得率高,脱木素选择性好。 It was critical to control the reaction pH at 7 .0 ~ 7 .5 by means of buffer when in sitegenerated DMD was employed in eucalyptus kraft pulp bleaching. Increasing the chemical chargesof permonosulfate and acetone resulted in increased DMD bIeaching effectiveness. Eucalyptus kraftpulp treated with 5% DMD, followed by an caustic extraction, had the same pulp Kappa number asthat treated with oxygen, while the pulp yield and delignification selectivity of DMD bleachingwere more superior than oxygen delignilication.
出处 《纤维素科学与技术》 CAS CSCD 1999年第2期16-21,共6页 Journal of Cellulose Science and Technology
关键词 桉木浆 硫酸盐浆 漂白 工艺 DMD 造纸 纸浆 dimethyldioxirane(DMD), eucalyptus kraft pulp, bleaching conditions
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  • 1张建功,黄干强,赖燕明,谢益民.马尾松硫酸盐木浆活性氧漂白的研究[J].中国造纸学报,1998,13(B12):14-20. 被引量:2
  • 2张巍,俞建勇,吴丽莉.竹纤维的DMD漂白工艺条件[J].纺织学报,2005,26(1):100-101. 被引量:3
  • 3黄干强,韩克涛,张曾,谢益民.DMD处理KP浆时残余木素结构的变化[J].中国造纸学报,1999,14(B10):36-43. 被引量:1
  • 4Murray R W, Jeyaraman R. Dioxirane: Synthesis and reaction ofmethyldioxiranes[J]. J Org Chem, 1985, 50(16): 2847-2853. 被引量:1
  • 5Montgomery R E. Catalysis of peroxymonosulfate reactions by ketones[J]. Journal of the American Chemical Society, 1974, 96(25): 7820-7821. 被引量:1
  • 6Adam W, Chan Y Y, Cremer D, et al. Spectral and chemical properties of dimethyldioxirane as determined by experiment and ab initio calculations[J]. J Org Chem, 1987, 52(13): 2800-2803. 被引量:1
  • 7Adam W, Curci R, Edwards J O. Dioxiranes: Anew class of powerful oxidants[J]. American Chemical Society, 1989, 22(6): 205-211. 被引量:1
  • 8Argyopoulous D S, Sun Y, Berry R M, et al. Reactions of dimenthydioxirane with lignin model compounds[J]. Journal of Pulp and Paper Science, 1996, 22(3): J84-J90. 被引量:1
  • 9Ragauskas A J. Investigation of dimethyldioxirane as a bleaching reagent for kraR pulp[J]. Tappi Journal, 1993, 76(7): 87-90. 被引量:1
  • 10秦文娟,梁文芷.新漂剂-二甲基二环氧乙烷[J].纸和造纸,1997,7(4):10. 被引量:1

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