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多孔介质中天然气水合物相平衡条件研究进展 被引量:2

Advance in Study of Natural Gas Hydrate Phase Equilibrium Condition in Porous Media
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摘要 天然气水合物主要赋存于各种沉积物孔隙之中,只有6%左右以块状纯水合物的形式存在。现在对于天然气水合物相平衡条件的研究主要集中在对多孔介质各因素的考察。就目前研究成果来看,理论预测自然条件中水合物稳定条件的准确性仍然较差,其主要原因:水合物稳定存在的天然条件影响因素远比实验室中(大多预测模型基于实验室建立)的影响因素复杂得多;实际中的介质微孔孔径并不恒定,呈分布状态,且分布比较复杂;自然条件下的多孔介质的成分、结构都非常复杂。 Natural gas hydrates mainly exist in fractures of seabed or permafrost sediments,and only six percent are bulk hydrates.Now,the most investigation of natural gas hydrate phase equilibrium condition mainly concentrate on the studies of pore structures.However,at present,the accuracy of theoretical predictions of natural gas hydrates stabilization conditions is still not satisfied.The main reasons are that:natural influencing factors of natural gas hydrates stabilization conditions are much more complex than the considering factors in laboratories,where the most prediction models were made;the natural radius of pores in porous media keeps not simple constant but complex distribution;the natural compositions and structures in porous media are very complex.
出处 《河北化工》 2010年第6期7-10,共4页 Hebei Chemical Industry
关键词 天然气水合物 多孔介质 相平衡条件 natural gas hydrates porous media equilibrium conditions
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  • 1贝克 C Ш,马科冈 I O Ф,福米纳 B И.气体水化物[M].北京:石油工业出版社,1987,44. 被引量:1
  • 2张欣利.海洋沉积物中的天然气水合物层及其成岩作用[A].见:史斗,孙成权,朱岳年等.国外天然气水合物研究进展[C].甘肃兰州:兰州大学出版社,1992.54-56. 被引量:2
  • 3Handa Y. P., Stupin D.. Thermodynamic properties and dissociation characteristics of methane and propane hydrates in 70 A radius silica gel pores [J]. The Journal of Physical Chemistry, 1992,96:8 599-8 603. 被引量:1
  • 4Uchida T, Ebinuma T., Ishizaki T. Dissociation condition measurements of methane hydrate in confined small pores of porousglass [J]. The Journal of Physical Chemistry B, 1999,103:3 659-3 662. 被引量:1
  • 5Balsam W. L, Damuth J. E..Further investigations of Ship board vs shore-based spectral data:Implications for interpreting Leg 164 sediment composition [A].Proceedings of Ocean Drilling Program, Seientie Results [C]. College Station, Tex:Texas A & M University, 2000,164. 被引量:1
  • 6Titiloye J.O.,Skipper N.T..Molecular dynamics simulation of methane in sodium montmotrillonite clay hydrates at elevated pressures and temperatures [J].Molecular Physics, 2001,99(10):899-906. 被引量:1
  • 7Smith D. H., Wilder J. W., Seshadri J.. Methane hydratr equilibria in silica gels with broad pore size distributions [J]. AIChE Journal, 2002,48(2):393-400. 被引量:1
  • 8Huang X, Margulis C. J., Berne K J. Domolecules as small as neopentane induce a hydrophobic response similar to that of large hydrophobic surfaces [J].The Journal of Physical Chemistry B, 2003,107(42):11 742-11 748. 被引量:1
  • 9Kalra &, Hummer G., Garde S.. Methane partition in gand transport in hydrated carbon nanotubes [J]. The Journal of Physical Chemisty B, 2004,108:544-549. 被引量:1
  • 10陆现彩,杨涛,刘显东,蒋少涌,吴能友.多孔介质中天然气水合物稳定性的实验研究进展[J].现代地质,2005,19(1):89-95. 被引量:20

二级参考文献55

  • 1龙学渊,袁宗明,倪杰.国外天然气水合物研究进展及我国的对策建议[J].勘探地球物理进展,2006,29(3):170-177. 被引量:22
  • 2Zhou L, Sun Y, Zhou Y. Enhancement of the methane storage on activated carbon by preadsorbed water [ J ]. AIChE Journal,2002, 48 (10): 2412 -2416. 被引量:1
  • 3Perrin A, Celzard A, Mareche J F, et al. Methane storage within dry and wet active carbons: A comparative study [ J]. Energy &Fuels, 2003, 17 (5): 1283-1291. 被引量:1
  • 4Perrin A, Celzard A, Mareche J F, et al. Improved methane storage capacities by sorption on wet active carbons [J]. Carbon, 2004, 42:1249 - 1256. 被引量:1
  • 5Collett T S, Wendlandt R F. Formation evaluation of gas hydrate-bearing marine sediments on the Blake Ridge with downhole geochemical log measurements [ A ]. Proceedings of Ocean Drilling Program, Scientic Results [ C ]. College Station, Texas: Texas A & M University, 2000. 164. 被引量:1
  • 6Balsam W L, Damuth J E. Further investigations of Shipboard vs shore-based spectral data: Implications for interpreting Leg164 sediment composition [ A ]. Proceedings of Ocean Drilling Program, Scientic Results [ C ]. College Station, Texas: Texas A & M University, 2000. 164. 被引量:1
  • 7Ouar H, Cha S B, Wildeman T R, et al. The formation of natural gas hydrates in water-based drilling fluids [ J]. Transactions of IChemE (A), 1992, 70:48-54. 被引量:1
  • 8Kotkoskie T S, Al-Ubaldi B, Wildeman T R, et al. Inhibition of gas hydrate in water-based drilling muds [ J ]. SPE Drilling Engineering, 1992, 7: 130 - 136. 被引量:1
  • 9Park S H, Sposito G. Do montmorillonite surface promote methane hydrate formation Monte carlo and molecular dynamics simulation [J]. The Journal of Physical Chemistry B, 2003, 107:2281 - 2290. 被引量:1
  • 10Titiloye J O, Skipper N T. Molecular dynamics simulation of methane in sodium montmorillonite clay hydrates at elevated pressures and temperatures [ J]. Molecular Physics, 2001, 99(10): 899 -906. 被引量:1

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