摘要
Gold nanoparticles with different morphologies, such as spindle, octahedron, and decahedron were obtained by using different molar ratios of HAuCl4/HEPES in the presence and absence of surfactants at room temperature.These nanoparticles were characterized by X-ray diffraction（XRD）, transmission electron microscopy（TEM）, high-resolution transmission electron microscopy（HRTEM）, scanning electron microcopy（SEM）, energy-dispersive X-rays analysis（EDX）, and selected area electron diffraction（SAED）.The kinetics of the formation of gold nanoparticles in HEPES buffer was studied by UV-visible spectrophotometer.The formation of gold nanoparticles was strongly dependent on the concentration of HEPES and pH value.The surfactants play a crucial role in the size and shape controlled synthesis of gold nanoparticles.
Gold nanoparticles with different morphologies, such as spindle, octahedron, and decahedron were obtained by using different molar ratios of HAuCl4/HEPES in the presence and absence of surfactants at room temperature.These nanoparticles were characterized by X-ray diffraction（XRD）, transmission electron microscopy（TEM）, high-resolution transmission electron microscopy（HRTEM）, scanning electron microcopy（SEM）, energy-dispersive X-rays analysis（EDX）, and selected area electron diffraction（SAED）.The kinetics of the formation of gold nanoparticles in HEPES buffer was studied by UV-visible spectrophotometer.The formation of gold nanoparticles was strongly dependent on the concentration of HEPES and pH value.The surfactants play a crucial role in the size and shape controlled synthesis of gold nanoparticles.
基金
supports from the Program for Excellent Talents of the Department of Education of Hubei Province, China (No. Q20081504)
the Area of Excellence Scheme administered by the University Grant Committee and the University of Hong Kong (No.AoE/ P-10/ 01)
