摘要
在较佳工艺条件下,用脉冲电位法合成了苯胺和二苯胺的聚合物膜,采用SEM观察了膜形貌,分别以红外光谱分析和循环伏安法研究了其电化学共聚合机理,采用电导率仪测定了其电导率。结果表明,用脉冲电位法合成的ANI-DPA聚合物膜具有较好的稳定性和较高的电导率。
The poly (ANI-co-DPA) membrane is synthesized using the pulse potential technique under the optimal process condition and its macroscopic is observed by SEM. The mechanism of the electrochemical co-polymerization is investigated by FTIR and the circle volt-ampere technique respectively and its conductivity are measured by conductivity meter. The experimental results show that the poly(ANI-co-DPA) membrane synthesized by this technique exhibits better stability and higher conductivity.
关键词
合成
聚合物膜
共聚合机理
synthesis, polymer membrane, mechanism of co-polymerization