摘要
A new method of recovery of phosphorus from high concentration phosphorous-containing pharmaceutical industry wastewater with composite calcium was proposed.It was found that the efficiency of phosphorous removal from the wastewater was affected by dosage of composite calcium,pH of solution,and the mole ratio of calcium chloride and calcium oxide in the composite calcium.The production of phosphorus residue,the available phosphorus(calculated as P2O5)and N,N-dimethylformaide(DMF)in the phosphorus residue were also determined.The content of phosphorus in the wastewater could be reduced from 31000 mg·L-1 to less than 0.5 mg·L-1,and the content of the available phosphorus in the phosphorous residue was about 18%,approaching the national standard for superior grade product of phosphorus fertilizer.Furthermore,the poisonous material DMF was not detectable in the residue by GC-MS and spectra photometry.
A new method of recovery of phosphorus from high concentration phosphorous-containing pharmaceutical industry wastewater with composite calcium was proposed.It was found that the efficiency of phosphorous removal from the wastewater was affected by dosage of composite calcium,pH of solution,and the mole ratio of calcium chloride and calcium oxide in the composite calcium.The production of phosphorus residue,the available phosphorus（calculated as P2O5）and N,N-dimethylformaide（DMF）in the phosphorus residue were also determined. The content of phosphorus in the wastewater could be reduced from 31000 mg · L%-1 to less than 0.5 mg · L^- 1, and the content of the available phosphorus in the phosphorous residue was about 18%, approaching the national standard for superior grade product of phosphorus fertilizer. Furthermore, the poisonous material DMF was not detectable in the residue by GCMS and spectra photometry.
出处
《化工学报》
EI
CAS
CSCD
北大核心
2009年第9期2346-2350,共5页
CIESC Journal
基金
武汉市攻关课题项目(200860423199)
湖北省攻关课题项目(2008BCB205)
关键词
含磷废水
复合钙盐
磷肥
DMF
phosphorus-containing wastewater
composite calcium
phosphate fertilizer
DMF
