摘要
本文在阐述普遍化微扰理论(GeneralizedPerturbationTheory)的基本方程式(简称GP方程)和两类控制反应的基础上,解释了一些亲电试剂或亲核试剂的双重反应性.作为GP方程的特例,用轨道相互作用图象解释某些有机分子的特定反应双重性:构型保持与构型转化等.
This paper explains the dualreaction nature of some electrophilic reagents and nucleophilic reagents, on the basis of elaborating generalized perturbation (GP) theory and two kinds of controlled reaction. As a special case of GP equation, by using orbital interaction pattern, the special dualreaction nature, configuration retaining and configuration inversion of some organic molecules are explained.
出处
《华北工学院学报》
1998年第2期185-188,共4页
Journal of North China Institute of Technology