摘要
研究了超声雾化进样系统在电感耦合等离子体原子发射光谱(ICP-AES)中的应用,考察了测定的影响因素。结果表明,超声雾化进样条件下,影响谱线强度和测量精密度的因素较多。其中影响较大的因素主要有:载气流量、进样速度、进样时间、冲洗条件及溶液的介质条件。载气的最大允许量远小于气动雾化中的常规用量。同时,进样时间对测量精密度的影响较大,而积分时间对测定的影响较小。此外,冲洗条件对记忆时间的影响较大,辅助冲洗水流的方式有助于减小记忆效应的影响。实验表明:超声雾化进样条件下,As,Pb,Se,Bi,Ge,Mo,Cd,Cu等八种元素的检出限低于气动雾化进样的检出限10～25倍,超声雾化进样技术在ICP-AES中的应用有助于改善ICP-AES测定的灵敏度。
The sample feeding system of inductively coupled plasma atomic emission spectrometry （ICP-AES） is pneumatic nebulization system, but its efficiency is not good. The ultrasonic nebulization technology possesses advantages of high nebulization efficient and fine droplets, and it is free of blocking phenomenon. It has good application perspective in nebulization technology. In the present paper the authors study the working conditions of ultrasonic nebulizer such as carrier gas flow, injection time, injection rate and mode of washing that are likely to affect the detection results, and study the detecting conditions of several elements such as As and Se etc. that have poorly detection limits in normal ICP-AES methods. At the same time, the application of them in biochemical samples was studied. Testing results show that carrier gas flow, injection rate and injection time can greatly affect the intensity of spectral lines, and the ultrasonic nebulizer sample feedifig system can increase the spectral line intensity and decrease the detection limit elements such as As, Pb, Se, Bi, Ge, Mo, Cd and Cu by about 10-25 times. Moreover, this ultrasonic nebulizer sample feeding system can reduce the time of memory effect by washing the sample cell.
出处
《光谱学与光谱分析》
SCIE
EI
CAS
CSCD
北大核心
2009年第8期2254-2257,共4页
Spectroscopy and Spectral Analysis
基金
国家自然科学基金项目(30760049
30640022)
云南省教育厅基金重点项目(08Z0028)资助
