摘要
建立了肉制食品中5种邻苯二甲酸酯类增塑剂（PAEs）含量的检测方法。样品用正己烷提取，C18柱分离，柱温35．0℃，乙腈-水为流动相梯度洗脱，流速1．0mL／min，紫外检测波长226nm。5种PAEs分离特异性好，在0．02～10μg／mL之间均具有较好的线性关系，检出限在4．4～13．8ng／mL之间，高、中、低3水平的回收率均在79．5％-102．0％之间，相对标准偏差均在1．1％-14％之间。方法适用于肉制食品中邻苯二甲酸酯类的检测。
A high performance liquid chromatographic method for the simultaneous determination of five kinds of phthalic acid esters （PAEs） in camose food was established. The samples were extracted by n-hexane and then separated on a C18 column, with the column temperature of 35 ℃. The mobile phase was composed of acetonitrile and water, and used with gradient ehition at the flow rate of 1.0 mL/min. The UV detection wavelength was 226 nm. The specificity was good. The standard curves were linear in the range of 0.02 to 10μg/mL, with the limits of detection ranging from 4.4 to 13.8 ng/mL. The recoveries ranged from 79.5% to 102.0%, and the relative standard deviations （RSD） from 1.1% to 14 %. The proposed method was simple and accurate, and could be applied to the determination of PikEs in camose food.
出处
《分析试验室》
CAS
CSCD
北大核心
2009年第6期49-52,共4页
Chinese Journal of Analysis Laboratory
基金
浙江省科技厅大型科学仪器设备协作共用平台科研计划(2007F70009)
浙江省新苗人才计划(2007R40G2070022)项目资助
