期刊文献+

铁氰化钴修饰玻碳电极的电化学行为研究

The Research on the Electrochemical Activity of the Cobalt Hexacyanoferrate Modified Glassy Carbon Electrode
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摘要 用镀膜/循环伏安法制备了铁氰化钴修饰玻碳电极,并以该电极为研究对象,采用循环伏安法考察了不同扫描速率对该电极电催化活性的影响及甲醇在该电极上的催化动力学行为。结果表明:铁氰化钴修饰玻碳电极表现出较高的对甲醇的电化学氧化催化活性,甲醇在该修饰电极上的电化学催化氧化是表面吸附控制过程。 The Cobalt Hexacyanoferrate modified glassy carbon electrode was fabricated through coating/cyclic vohammetry method, the effect of different scan rates on its electrochemical activity and the catalytic kinetics of methanol oxidation on it were investigated. The results showed that the Cobalt Hexacyanoferrate modified glassy carbon electrode had a high electrochemical catalytic activity on methanol oxidation, and the electrochemical catalytic oxidation of the methanol was a surface adsorption controlled nrocess.
机构地区 长治学院生化系
出处 《长治学院学报》 2009年第2期13-14,共2页 Journal of Changzhi University
关键词 铁氰化钴修饰玻碳电极 电化学 循环伏安 催化动力学 Cobalt Hexacyanoferrate modified glassy carbon electrode electrochemical cyclic-voltammetry catalytic kinetics
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参考文献6

  • 1王海燕,康龙华,鲁小俊,胡效亚.铁氰化钴-多壁碳纳米管修饰电极测定鸟嘌呤[J].扬州大学学报(自然科学版),2006,9(2):26-30. 被引量:6
  • 2都君华,李伟善,李红,黄启明,陈红雨,袁中直.氢钼青铜修饰铂电极对甲醇氧化的电催化作用[J].精细化工,2002,19(10):511-514. 被引量:4
  • 3董绍俊等著..化学修饰电极[M].北京:科学出版社,2003:641.
  • 4顾登平,童汝亭编著..化学电源[M].北京:高等教育出版社,1993:142.
  • 5邓勃等著..仪器分析[M].北京:清华大学出版社,1991:519.
  • 6C. F. Zinola,A. M. Castro Luna,W. E. Triaca,A. J. Arvia. Kinetics and mechanism of the electrochemical reduction of molecular oxygen on platinum in KOH: influence of preferred crystallographic orientation[J] 1994,Journal of Applied Electrochemistry(6):531~541 被引量:1

二级参考文献24

  • 1田立朋,李伟善,李红.Pt/H_xMoO_3电极上甲醇的催化氧化[J].精细化工,2000,17(z1):107-110. 被引量:8
  • 2Lamy C. Electrocatalytic oxidation of organic compounds on noble metals in aqueous solution[J].Electrochimica Acta,1984,29(11):1581-1588. 被引量:1
  • 3M Watanabe,M Uchida ,S Motoo.Application of the gas diffusion electrode to a bachward feed and exhaust(bfe) type methanol anode[J].J Electroananl Chem,1986,199:311-322. 被引量:1
  • 4Appleby J.The energy crisis.The electrochemical viewpoint[J].J Electroanal Chem,1981,118:31-50. 被引量:1
  • 5S.Srinivasa.Fuel cell for electric utility and transportation application[J].J Electroanal Chem ,1981,118:51-69. 被引量:1
  • 6McNicol B D, Rand D A J, Williams K R. Direct methanol-air fuel cells for road transportation[J].J Power Source,1999,83:15-31. 被引量:1
  • 7M Baldauf, W Preidel. Status of the development of a direct methanol fuel cell[J].J Power Source,1999,84:161-166. 被引量:1
  • 8Shropshire J A.A unifying scheme for the electrochemical oxidation of carbonaceous fuels on platinum in sulphuric acid[J].Electrochim Acta,1967,12:253-258. 被引量:1
  • 9W S Li,L P Tian,Q M Huang,et al. Catalytic oxidation of methanol on molybdate-modified platinum electrode in sulfuric acid solution[J].J Power Source,2002,104:281. 被引量:1
  • 10H Q Zhang, Y Wang, E R Fachin,et al.Electrochemically codeposited platinum/molybdenum oxide electrode for catalytic oxidation of methanol in acid solution[J].Electrochemical and Solid-State Letters,1999,2(9):437-439. 被引量:1

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