摘要
以月桂酸和二氯亚砜为原料,合成十二酰氯;十二酰氯与苯在三氯化铝催化下合成十二酰基苯;混酸硝化十二酰基苯合成间硝基十二酰基苯;间硝基十二酰基苯经催化氢化还原得到间氨基十二烷基苯。产物结构经1HNMR,MS确认。
Lauric chloride was firstly synthesized by using laurie acid and thio nyl chloride as the raw materials, laurie benzene was synthesized by the Frie-del-Crafts reaction, then the lauric benzene was nitrified to obtain m-nitryllau-ric benzene, and finally m- dodecylanline was obtained by the catalytic hydro genation of 3-nitryl-lauric benzene.The structure of the product was characterized by ^1HNMR, and MS spectra.
出处
《浙江化工》
CAS
2009年第4期9-11,共3页
Zhejiang Chemical Industry
关键词
月桂酸
间硝基十二烷基苯
间十二烷基苯胺
中间体
合成
m-dodecylanline
lauric acid
m-nitryl-lauric benzene
chemical intermediate
synthesis
