摘要
关于取代基对苯甲酸酸性强弱的影响,应综合考虑电子效应、氢键、立体效应和邻位效应等多方面因素.本文用轨道理论解释邻位效应,能更好地理解邻位取代苯甲酸的酸性显著的增加.
The influence of the substituting group to benzoic acid is the result of induced effect,conjugate effect,ort-position effect and stereo hindrance effect.On the other hand,it analyses ort-position effect by orbital theory,and understand the acid is increase obviously,when ort-position replaces benzoic.
出处
《淮北煤师院学报(自然科学版)》
1998年第1期59-63,共5页
Journal of Huaibei Teachers College(Natural Sciences Edition)
关键词
苯甲酸
酸性
取代苯甲酸
substituting group benzoic acid effect