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RESEARCH OF STEREOCHEMISTRY ON PRINS REACTION OF CYCLOHEXENE 被引量:1

RESEARCH OF STEREOCHEMISTRY ON PRINS REACTION OF CYCLOHEXENE
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摘要 The Prins reaction between most olefins and formaldehyde shows non-stereospecificity and region selectivity. All the additions of halostyrene, cyclopentene and other olefms are conducted through open ion mechanism. However, the Prins reaction of cyclohexene with water or acetic acid as solvent gives the trans-product stereospecifically with excellent yield. It is considered that the Prins reaction of cyclohexene different from the addition of other
出处 《Chinese Science Bulletin》 SCIE EI CAS 1989年第24期2045-2049,共5页
基金 The note is a related work of the research subiects supported by the National Natural Science Foundation of China
关键词 mechanism of ELECTROPHILIC addition orbital DOMINATION rule PRINS reaction NMR basketed solvent effect DONOR-ACCEPTOR bond. mechanism of electrophilic addition orbital domination rule Prins reaction NMR basketed solvent effect donor-acceptor bond.
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