摘要
文章介绍了鲍林价键理论的思想起源和形成过程:接受路易斯的化学键电子理论;吸取海森伯的量子共振概念;得到海特勒和伦敦对氢分子结构近似处理的启发;从而完善了价键理论,提出了电子对键的六条规则;解决了碳原子四面体构型的问题,建立了杂化轨道理论。
The origin and forming of Pauling＇s valence bond theory is introduced： Lewis＇s electron theory of the chemical bond,heisenberg＇s quantum resonance concept,Heitler and London＇ approximate treatment of the structure of the hydrogen molecule.The valence bond theory was perfected;The properties of the electron-pair bond was proposed;The problem of the tetrahedra configuration of carbon atom was resolved;theory of hybrid bond orbitals was established.
出处
《自然杂志》
北大核心
2009年第1期47-54,共8页
Chinese Journal of Nature
关键词
价键理论
量子共振
电子对键
四面体构型
杂化轨道
valence bond theory,quantum resonance,electron-pair bond,tetrahedra configuration,hybrid bond orbitals
