摘要
过渡金属钴取代的钨镓杂多化合物的导电性＊王力刘宗瑞周云山王恩波＊＊（东北师范大学化学系长春１３００２４关键词钨镓杂多配合物电导率固体电解质高质子导体中图分类号Ｏ６４１．４取代型杂多化合物的独特结构以及优异性能日益受到人们的重视［１］。我们在从事多酸研...
The substituted tungstogallate complexes Na 7[GaW 11 Co(H 2O)O 39 ]·16H 2O,Na 7H 2[GaW 10 Co 2(H 2O) 2O 38 ·16H 2O,α Na 7H 4[GaW 9Co 3(H 2O) 3O 37 ]·16H 2O were synthesized and characterized by IR,UV,ICP,TG DTA, 183 WNMR, ESR.Determination of the conductivity exhibits that such complexes are excellent high proton conductor.In which, σ value of GaW 9Co 3 is above 10 -3 s·cm -1 at room temperature and 10 -2 s·cm -1 at 343K.The compounds may be espected to serve as new practical solid electrolyte.
出处
《化学研究与应用》
CAS
CSCD
1997年第3期277-280,共4页
Chemical Research and Application
基金
国家自然科学基金
南京大学配位化学国家重点实验室基金
吉林大学水热合成实验室基金
