摘要
用固相合成法,以Keggin结构稀有金属一取代杂多钨硅酸盐异构体α,βi-[SiW11Ti(H2O)O39]4-和α,βi-[SiW11Nb-(H2O)O39]3-为掺杂剂制备了8种聚苯胺掺杂材料。用红外光谱和紫外光谱等测试手段对其进行分析,研究了它们的热稳定性、导电性和荧光性。
Eight polyaniline hybrid materials doped with rare metal monosubstituted Keggin structure silicotungstate anions α,βi-[SiW11Ti(H2O)O39]^4- , α,βi-[SiW11Nb(H2O)O39]^3-were prepared by solid-state synthesis method.The materials were characterized by IR spectroscopy and UV-Vis diffraction. In addition, their thermal stability, conductivity and fluorescence property were studied.
出处
《化学试剂》
CAS
CSCD
北大核心
2008年第3期168-170,174,共4页
Chemical Reagents
基金
黑龙江省自然科学基金资助项目(B2007-15)
关键词
聚苯胺
硅钨酸盐
荧光性
导电性
polyaniline
silicotungstate
fluorescence property
conductivity