摘要
通过土柱实验,研究了污泥中几种重金属元素Cu,Zn,Ni,Ph的运移特点和形态。实验表明,表层4cm土壤混入6%的污泥后,显著增加了Cu,Ni,Zn的淋出量.而Ph没有显著增加。淋出液中Cu,Ni几乎都是配位态重金属,Zn则有较高比例的非配位态离子。土壤对Cu2+的吸附能力大于Zn2+,Cu2+与有机物的配位能力强于Zn2+。水溶性有机物与重金属的配位反应对Cu,Ni运移影响较大。Zn的运动则主要受土壤的吸附作用和配位反应的影响。
A soil column experiment and an incubation experiment were conducted to study the mobility and forms of Cu,Ni,Zn,Pb in sludge-soil system. The results indicated that Cu,Ni,Zn in elution increased significantly when 1. 5g sewage sludge was mixed with the top 4cm soil (6% sewage sludge in the top 4cm soil). Pb didn't increase. Nearly all the Cu and Ni in the elution were in complexion forms. Zn had higher proportion of non-complexion forms. The soil absorption capacity to Cu is higher than that to Zn, and Cu-binding capacity with organic matter is higher than that of Zn. The complexion capacities of Cu and Ni with water-soluble organic matter are important factors to influence theis mobility. For Zn, the soil absorption capacity affects Zn mobility much.
出处
《中国农业大学学报》
CAS
CSCD
北大核心
1997年第3期113-118,共6页
Journal of China Agricultural University
关键词
污泥
重金属
运移
形态
砂土
sewage sludge
heavy metals
mobility
forms
sandy soil