摘要
室温下,1-乙酰基薁-3-甲酸甲酯与N,N-二甲酰胺缩甲醛缩合后再与肼或苯肼反应,合成了6个新的1-(3-吡唑基)薁类衍生物,其结构经1HNMR,MS和元素分析表征。并对反应机理进行了探讨。
Six novel methyl 1-（pyrazol-3-yl）-azulene-3-carhoxylates derivatives were synthesized by the condensation of methyl 1-acetylazulene-3-carhoxylate with formamide dimethylacetal and then reaction with hydrazine or phenyl hydrazine. The structures were confirmed by ^1H NMR, MS and elemental analysis.
出处
《合成化学》
CAS
CSCD
2007年第6期702-705,718,共5页
Chinese Journal of Synthetic Chemistry
基金
辽宁省教育厅科学研究计划资助项目(2005021)
关键词
薁
吡唑
烯胺酮
N
N-二甲酰胺缩甲醛
肼
合成
azulene
pyrazole
enaminone
dimethylformamide dimethylacetal
hydrazine
synthesis
