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氢化物发生-原子荧光法测定纯铜中镉 被引量:13

Hydride Generation-Atomic Fluorescence Spectrometric Determination of Cadmium in Pure Copper
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摘要 用717阴离子交换树脂填充柱选择性吸附CdCl4^2-阴离子,以实现其与大量铜基体的分离。在标准溶液中匹配适当基体浓度并采用氢化物发生.原子荧光法,实现了铜/镉质量比为2000—50000的纯铜中痕量镉的测定。在基体铜的浓度为50mg/L的样品消化液中,镉的检出限为0.2μg/L;精密度为3.0%(n=7,3.0μg/L),镉浓度在1.0—25.0μg/L范围内呈良好线性关系。本法适用于纯铜中痕量镉的测定。 An anion exchange-sequential injection-hydride generation-atomic fluorescence spectrometric procedure was developed for the determination of ultra-trace cadmium in pure copper forbidden by the Restriction of the use of Hazardous Substances in Electrical and Electronic Equipment (RollS). A 50-mg/L copper concentration was employed in the standard solutions in order to match the copper matrix in the samples. In the presence of appropriate amount of hydrochloric acid, the copper matrix was effectively eliminated by selectively absorbing the CdCl4^2- complex onto a 717 anion exchanger packed mini-column. The present procedure could be used for the determination of cadmium in pure copper with a Cu/Cd mass ratio in the range of 2000 - 50000. A detection limit of 0.2μg/L was achieved within a linear range of 1.0 - 25.0μg/L, along with a RSD value of 3.0% (at 3.0μg/L, n =7 ). The procedure was applied for the determination of cadmium in a pure copper sample, and spiking recoveries were also performed.
出处 《分析化学》 SCIE EI CAS CSCD 北大核心 2007年第9期1339-1342,共4页 Chinese Journal of Analytical Chemistry
基金 国家自然科学基金(No.20575010) 教育部科学研究重点项目(No.105056) 教育部博士点基金(No.20050145026)资助
关键词 阴离子交换 氢化物发生-原子荧光 纯铜 Anion exchange, hydride generation-atomic fluorescence spectrometry, cadmium, pure copper
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